Ion Adsorption Science and Technology Group

Time:2024-10-18

1. Research Group

      Ion Adsorption Science and Technology Group

2. Brief Introduction

   The Ion Adsorption Science and Technology Group focuses on addressing the national demand for efficient development of strategic resources in salt lakes, with a research emphasis on dispersed elements in salt lakes. We conduct in-depth studies on interfacial ion transport mechanisms and construct adsorption separation materials. By precisely regulating adsorption sites and pathways within materials and enhancing performance on multiple scales, we aim to increase the recovery efficiency of strategic elements from salt lakes and achieve green, efficient separation of key strategic resources.

    The research group currently has 30 members, including 9 full-time staff (1 professor and 3 associate professors). The team is dedicated to the design and synthesis of adsorbents, studies on adsorption mechanisms, and the development of adsorption-separation processes. Our focus includes the extraction or removal of lithium, rubidium, cesium, boron, iodine, and other valuable elements from salt lakes. We design and prepare effective composite and electroactive adsorbents and systematically investigate their functional structures, adsorption/desorption capabilities, and recycling performance. Adsorption mechanisms are explored in depth from the perspectives of electrostatic, hydrophobic, hydrogen bond, precipitation, and coordination interactions, with a goal of developing separation processes for specific application scenarios.

3. Introduction of The Group Director

Name: Dr./Prof. Zhong Liu

Major: Ion Adsorption Science and Technology

Tel: +86-(0)15297182595

E-mail: liuzhong@isl.ac.cn

Brief CVZhong Liu, PhD/Professor, doctoral supervisor. He graduated from China University of Geosciences (Wuhan) in July 2007, with a bachelor's degree in Materials Science and Engineering and a master's degree in Petrology and Mineral Material Science. He earned his Ph.D. in Materials Science from the Institute of Coal Chemistry, Chinese Academy of Sciences, in July 2012. He visited the University of St Andrews in the United Kingdom twice, in 2014-2015 and 2018, for further study. Since graduation, he has been conducting research on ion adsorption and separation at the Qinghai Institute of Salt Lakes, CAS. His career path includes Research Trainee (2007.07-2012.06), Assistant Researcher (2012.07-2016.06), Associate Researcher (2016.06-2021.09), and Professor (2021.10-present).

Research Fields:

1.Adsorption Surface and Interface Chemistry: Focusing on the adsorption separation of salt lake resources, conducting research related to crystal ion transport in adsorption materials at the liquid-solid interface, surface structure optimization, interfacial structure control, and the assembly of separation devices.

2.Adsorption Separation Science and Technology: Optimization of adsorption towers and intensification of adsorption process techniques, exploring ion desorption with electric field assistance, achieving efficient separation of cations and anions. The work also involves developing integrated technology for extracting lithium, cesium, bromine, boron, and other resources from salt lakes, combining it with traditional adsorption technologies.

      Professor Liu has published over 30 SCI papers as the first or corresponding author and holds 10 patents. He has been selected as a Youth Scholar for Regional Development by the Chinese Academy of Sciences, a leading talent in Qinghai's "Kunlun Talent - High-end Innovation and Entrepreneurship Talent" program, and a discipline leader in Natural Science and Engineering in Qinghai Province. He is a member of the Youth Innovation Promotion Association of the Chinese Academy of Sciences and was selected for the "Western Light" Youth Scholar A-Class Talent Program. He has led three National Natural Science Foundation projects, six provincial and ministerial projects, and has been the principal investigator of a youth team project funded by the CAS for fundamental research.

4. Group members

(1) Staffs

(2) Master’s Degree Students

5. Research Projects

[1]     Green and Efficient Separation of Key Strategic Resources from Salt Lakes: Youth Team Program in Fundamental Research, Chinese Academy of Sciences, July 2022 - July 2027, 20 million RMB.

[2]      Optimization of Lithium Adsorption Performance from Brine and Efficient Lithium-Boron Separation: National Natural Science Foundation – Regional Innovation Development Joint Fund (Key Support Project), January 2021 - December 2024, 2.6 million RMB.

[3]      Development of Multi-Gradient Confinement-Enriched Lithium Adsorption and Separation Membrane: National Natural Science Foundation – Regional Innovation Development Joint Fund (Key Support Project), January 2024 - December 2027, 2.6 million RMB.

[4]      Development of Stable Rubidium and Cesium Ion Magnetic Adsorbent and Study of Surface Mechanics: National Natural Science Foundation – Qaidam Salt Lake Chemical Science Joint Fund (Cultivation Project), January 2017 - December 2019, 550,000 RMB.

[5]      Effect of Magnetic Iron Oxide Crystal Face Regulation on Cesium Ion Adsorbent Grafting Performance: National Natural Science Foundation Youth Project, January 2014 - December 2016, 240,000 RMB.

[6]      Development of Lithium Extraction Process in Salt Lakes Based on Electrically Controlled Ion Exchange: Qinghai Province Science and Technology Achievement Transformation Project, January 2024 - December 2025, 1.5 million RMB.

[7]      Development of Lithium Adsorbent for Salt Lakes and Stepwise Electric Field Assisted Desorption Process: Qinghai Province Science and Technology Achievement Transformation Project, January 2018 - December 2021, 3 million RMB.

[8]      Construction and Structure-Activity Relationship Study of Graphene Oxide-Based Composite Aerogels for Uranium Extraction from Salt Lakes: Qinghai Province Natural Science Foundation, March 2023 - December 2025, 300,000 RMB.

[9]      Study on the Structural Regulation and Anti-Dissolution Properties of Manganese-Based Lithium Ion Sieves: Qinghai Province International Cooperation Project, January 2019 - December 2021, 450,000 RMB.

[10]  Preparation of Magnetic Materials and Magnetic Adsorbents: Youth Innovation Promotion Association of the Chinese Academy of Sciences, January 2016 - December 2019, 700,000 RMB.

[11]  Design and Preparation of New Cesium Ion Magnetic Adsorbent: Western Light Talent Project of the Chinese Academy of Sciences, January 2016 - December 2018, 500,000 RMB.

[12]  Construction of Biomimetic Superhydrophobic Anti-Corrosion Coating on Magnesium Alloy Surface: Western Light Talent Project of the Chinese Academy of Sciences, January 2019 - December 2021, 150,000 RMB.

[13]  Study on the Effect of Iron Oxide Crystal Face Properties on Cesium Ion Magnetic Adsorbent: Qinghai Province Natural Science Foundation Youth Project, July 2014 - July 2017, 100,000 RMB.

[14]  Construction of Electrically Controlled Selective Permeation Membrane Based on H1.6Mn1.6O4 and Study of Mass Transfer Mechanism: Qinghai Province Applied Basic Research Project, January 2023 - December 2024, 300,000 RMB.

[15]  Construction of Organic-Inorganic Hybrid Superhydrophobic Coating on Magnesium Alloy Surface and Its Anti-Corrosion Mechanism in High Salt Environment: Qinghai Province Natural Science Foundation Youth Fund, January 2019 - December 2021, 300,000 RMB.

[16]  Study on the Competitive Adsorption Mechanism and Electrode Modification of Lithium Extraction from Salt Lake Brine by Electrochemical Ion Pump: Qinghai Province Natural Science Foundation Youth Project, January 2023 - December 2025, 150,000 RMB.

[17]  Research on Lithium Extraction from Tibetan Salt Lakes Using Electrically Controlled Ion Sieves: Wanhua Chemical Group Co., Ltd., June 2022 - May 2025, 1.2 million RMB.

[18]  Phase Equilibrium and Theoretical Simulation Study of Lithium-Containing Salt Lake Brine System from Low to Room Temperature: Qinghai Province Natural Science Foundation - Youth Fund, January 2022 - December 2024, 150,000 RMB.

[19]  Study on Chloride Ion Removal Mechanism Based on In-Situ Raman Analysis of Polyaniline Battery Deionization Technology: National Natural Science Foundation - Youth Fund, January 2023 - December 2025, 300,000 RMB.

[20]  Study on the Mechanism of Ion Selective Extraction Using Potentially Controllable Polyketone Materials in Battery Deionization Technology: Youth Innovation Promotion Association of the Chinese Academy of Sciences, January 2023 - December 2026, 800,000 RMB.

[21]  Research and Development of Multifunctional Materials for Ion Selective Extraction Using Electrical Potential Differentiation: Key Talent Project, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, October 2022 - October 2024, 200,000 RMB.

[22]  Study on Bromine Extraction from Salt Lake Brine Using Modified Polyaniline Battery Deionization Technology: Qinghai Province Basic Research Program - Natural Science Foundation - Youth, January 2024 - December 2016, 100,000 RMB.

[23]  Study on the Diffusion Adsorption Separation Mechanism of Light Metal Ions Based on Multi-Scale Theoretical Simulation: Key Talent Project, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, April 2024 - April 2027, 400,000 RMB.

[24]  Study on the Effect of Fluorescent Probe Ester Recognition Site Affinity on Trace Hydrazine Response Rate: National Natural Science Foundation Youth Fund, January 2024 - December 2026, 300,000 RMB.

[25]  Design of Metal-Organic Framework Sensing Materials for Ultralow Detection of Explosive Hazardous Chemicals: Special Research Assistant Funded Project, Chinese Academy of Sciences, January 2021 - January 2024, 900,000 RMB.

[26]  Study on the Encapsulation of Alkaline Proteins by Calcium Carbonate Microspheres Doped with Polyanionic Electrolytes: Wenzhou Science and Technology Bureau Industrial Science and Technology Project, January 2016 - December 2017, 40,000 RMB.

6. Publications

(1) Papers

[1]     Shi P., Wang K., Chen Z., Wang J., Lin K., Solange N., Yue Y., Guo Z., Symmetric variation of monomers for constructing 1D/2D imine-based covalent organic frameworks. CCS Chemistry, 2024, 6, 941-952.

[2]     She J., Chen X., Gao H., Song Z., Shi L., Li J., Lu X., Wu C., ‘Green’ fabrication of PVC ultrafiltration membranes with high-flux and improved hydrophilicity by in-situ interpenetration of hydrophilic crosslinking networks. Journal of Membrane Science, 2024, 693, 122383.

[3]     Qiao Y., Dai X., Zhao B., Qian Z., Wu Z., Liu Z., Enhanced lithium extraction from aqueous solutions using multi-scale modified titanium adsorbent. Separation and Purification Technology, 2024, 351, 128060.

[4]     Wu Y., Lei D., Li J., Luo Y., Du Y., Zhang S., Zu B., Su Y., Dou X., Controlled synthesis of preferential facet-exposed Fe-MOFs for ultrasensitive detection of peroxides. Small, 2024, 20, 2401024.

[5]     Luo Y., Lei D., Li M., Ge Y., Li J., Zu B., Yao J., Dou X., Fluorophore branching boosted photo-induced energy transfer in UiO-66 for ultrasensitive and instant hydrazine sensing. Journal of Materials Chemistry A, 2024, 12, 12088-12097.

[6]     Feng Y., Lei D., Zu B., Li J., Li Y., Dou X., A self-accelerating naphthylamide-based probe coupled with up-conversion nanoparticles for ultra-accurate tri-mode visualization of hydrogen peroxide. Advanced Science, 2024, 11, 2309182.

[7]     Xiao F., Lei D., Liu C., Li Y., Ren W., Li J., Li D., Zu B., Dou X., Coherent modulation of the aggregation behavior and intramolecular charge transfer in small molecule probes for sensitive and long-term nerve agent monitoring. Angewandte Chemie International Edition, 2024, 63, e202400453.

[8]     She J., Gao H., Song Z., Shi L., Li J., Lu X., Wu C., Improvement of persistent hydrophilicity and pore uniformity of polyvinyl chloride ultrafiltration membranes by in-situ crosslinking reaction assisted phase separation. Journal of Membrane Science, 2023, 684, 121884.

[9]     She J., Gao H., Song Z., Shi L., Liu S., Li J., Lu X., Wu C., N-methylglucamine modified poly (vinyl chloride) support assists the construction of uniform dually charged nanofiltration membrane via interfacial polymerization. Separation and Purification Technology, 2023, 307, 122674.

[10] Shi P., Wang J., Guo Z., A one-dimensional covalent organic framework film for near-infrared electrochromism. Chemical Engineering Journal, 2023, 451139082.

[11] Zhao B., Qiao Y., Qian Z., Wei W., Li J., Wu Z., Liu Z., Unraveling the Li+ desorption behavior and mechanism of Li4Ti5O12 with different facets to enhance lithium extraction. Journal of Materials Chemistry A, 2023, 11, 7094-7104.

[12] Sun C., Zhao B., Mao J., Dai K., Wang Z., Tang L., Chen H., Zhang X., Zheng J., Enhanced cycling stability of 4.6 V LiCoO2 cathodes by inhibiting catalytic activity of its interface via mxene modification. Advance Functional Materials, 2023, 33, 2300589.

[13] Chen Y., Zhan H., Qiao Y., Qian Z., Lv B., Wu Z., Liu Z., Facet dependent ion channel of iron phosphate for electrochemical lithium extraction. Chemical Engineering Journal, 2023, 477, 147136.

[14] Zhan H., Qiao Y., Qian Z., Li J., Wu Z., Liu Z., Electrochemical behaviors of porous spherical spinel H1.6Mn1.6O4 with high Li+ adsorption capacity. Separation and Purification Technology. 2023, 305, 122485.

[15] Zhao B., Qian Z., Qiao Y., Li J., Wu Z., Liu Z., The Li(H2O)n dehydration behavior influences the Li+ ion adsorption on H4Ti5O12 with different facets exposed. Chemical Engineering Journal, 2023, 451, 138870-138882.

[16] Shi P., Qin Ji., Luo S., Hao P., Li N., Zan X., Effect of the stiffness of one-layer protein-based microcapsules on dendritic cell uptake and endocytic mechanism, Biomaterials Science. 2022, 10, 178-188.

[17] Nie G., Cui R., Li W., Stable Phase equilibria of the quaternary system LiBr-NaBr-KBr-H2O and the ternary system LiBr-KBr-H2O at 323.15 K. Journal of Chemical & Engineering Data, 2022, 68, 229-235.

[18] Nie G., Cui R., Liu Z., Li W., Solid-liquid phase equilibria of quaternary system LiBr-NaBr-KBr-H2O and its subsystems at 348.15 K. ACS Omega, 2022, 7, 46594-46601.

[19] Zhan H., Qiao Y., Qian Z., Li J., Wu Z., Hao X., Liu Z., Manganese-based spinel adsorbents for lithium recovery from aqueous solutions by electrochemical technique. Journal of Industrial and Engineering Chemistry, 2022, 114:142-150.

[20] Qian Z., Liu Z., Wang S., Ye X., Wu Z., Preparation and anti-corrosion properties of SiO2@MWCNTs@PFOTES superhydrophobic coatings on magnesium alloy. International Journal of Electrochemical Science. 2022, 17, 220129.

[21] Liu H., Tian D., Ouyang M., Qian Z., Wang X., Morphology-controlled fabrication of magnetic phase-change microcapsules for synchronous efficient recovery of wastewater and waste heat. J. Colloid Interface Sci., 2022, 608, 1497.

[22] Shi P., Qin J., Wu X., Wang L., Zhang T., Yang D., Zan X., Appelhans D., Sheltering proteins from protease-mediated degradation and a de novo strategy for preventing acute liver injury. Biomaterials Science, 2021, 9, 4423-4427.

[23] Shi P., Zhou D., Zhu Y., Peng B., Shao N., Zan X., Thrombin-loaded TA-CaCO3 microspheres as a budget, adaptable, and highly efficient hemostatic. ACS Applied Bio Materials, 2021, 4, 1030-1037.

[24] Liu H., Zheng Z., Qian Z., Wang Q., Wu D., Wang X., Lamellar-structured phase change composites based on biomass-derived carbonaceous sheets and sodium acetate trihydrate for high-efficient solar photothermal energy harvest, Solar Energy Materials and Solar Cells, 2021, 229, 111140.

[25] Liu H., Qian Z., Wang Q., Wu D., Wang Xi., Development of renewable biomass-derived carbonaceous aerogel/mannitol phase-change composites for high thermal-energy-release efficiency and shape stabilization, ACS Applied Energy Materials, 2021, 4, 1714-1730.

[26] Qian Z., Liu Z., Wang S., Ye X., Wu Z., A durable PVDF/PFOTES-SiO2 superhydrophobic coating on AZ31B Mg alloy with enhanced abrasion resistance performance and anti-corrosion properties. Applied Sciences-Basel, 2021, 11(23), 11172.

[27] Qian F., Zhao B., Guo M., Wu Z., Zhou W., Liu Z., Surface trace doping of Na enhancing structure stability and adsorption properties of Li1.6Mn1.6O4 for Li+ recovery. Separation and Purification Technology, 2021, 256, 117583-117593.

[28] Zhao B., Qian F., Guo M., Wu Z., Liu Z., The performance and mechanism of recovering lithium on H4Ti5O12 adsorbents influenced by (110) and (111) facets exposed. Chemical Engineering Journal, 2021, 414, 128729.

[29] Qian F., Guo M., Qian Z., Zhao B., Li J., Wu Z., Liu Z., Enabling highly structure stability and adsorption performances of Li1.6Mn1.6O4 by Al-gradient surface doping. Separation and Purification Technology, 2021, 264, 118433-118443.

[30] Nie G., Sang S., Ye C., Gao Y., He C., Solubilities of salts in quaternary system KBr-K2SO4-K2B4O7-H2O and quinary system KCl-KBr-K2SO4-K2B4O7-H2O at 373 K. Russian Journal of Physical Chemistry A, 2021, 95, 1372-1377.

[31] Nie G., Cui R., Sang S., Wu Z., Ye C., Experimental study and theoretical simulation of fluid phase equilibrium in the subsystems of quinary system NaBr-KBr-MgBr2-SrBr2-H2O at 298 K. Journal of Molecular Liquids, 2020, 306, 112635.

[32] Nie G., Sang S., Cui R., Wu Z., Ye C., Gao Y., Measurements and calculations of solid-liquid equilibria in two quaternary systems: LiCl-NaCl-SrCl2-H2O and LiCl-KCl-SrCl2-H2O at 298 K. Fluid Phase Equilibria, 2020, 509, 112458.

[33] Wang S., Ye X., Zhang H., Qian Z., Li Q., Wu Z., Li S., Superhydrophobic silane/fluorinated attapulgite@SiO2 composite coatings on magnesium alloy for corrosion protection. ChemistrySelect, 2020, 5, 10329-10338.

[34] Qian F., Zhao B., Guo M., Qian Z., Wu Z., Liu Z., Trace doping by fluoride and sulfur to enhance adsorption capacity of manganese oxides for lithium recovery. Materials & Design, 2020, 194, 108867-108878.

[35] Qian F., Zhao B., Guo M., Qian Z., Xu N., Wu Z., Liu Z., Enhancing the Li+ adsorption and anti-dissolution properties of Li1.6Mn1.6O4 with Fe, Co doped. Hydrometallurgy, 2020, 193, 105291-105298.

[36] Qian F., Zhao B., Guo M., Li J., Liu Z., Wu Z., K-Gradient Doping to Stabilize Spinel Structure of Li1.6Mn1.6O4 for Li+ Recovery. Dalton Transactions, 2020, 49, 10939-10949.

[37] Zhao B., Guo M., Qian Z., Li J., Wu Z., Liu Z., The adsorption behavior of lithium on spinel titanium oxide nanosheets with exposed (114) high-index facets. Dalton Transactions, 2020, 49, 14180-90.

[38] Zhao B., Guo M., Qian F., Qian Z., Xu N., Wu Z., Liu Z., Hydrothermal synthesis and adsorption behavior of H4Ti5O12 nanorods along [100] as lithium ion-sieves. RSC Advances, 2020, 10, 35153-35163.

[39] Xu N., Li S., Li W., Liu Z., Removal of fluoride by graphene oxide/alumina nanocomposite: adsorbent preparation, characterization, adsorption performance and mechanisms. ChemistrySelect, 2020, 5, 1818-1828.

[40] Cao Y., Wang H., Ding R., Wang L., Liu Z., Lv B., Highly efficient oxidative desulfurization of dibenzothiophene using Ni modified MoO3 catalyst. Applied Catalysis A: General, 2020, 589, 117308.

[41] Shi P., Qin J., Wu X., Wang L., Zhang T., Yang D., Zan X., Appelhans D., A facile and universal method to efficiently fabricate diverse protein capsules for multiple potential applications. ACS Applied Materials & Interfaces, 2019, 11(42): 39209-39218.

[42] Shi P., Qin J., Hu J., Bai Y., Zan X., Insight into the mechanism and factors on encapsulating basic model protein, lysozyme, into heparin doped CaCO3. Colloids and Surfaces B: Biointerfaces, 2019, 175, 184-194.

[43] Nie G., Sang S., Cui R., Measurements of the solid-liquid phase equilibria in quinary system NaBr-KBr-MgBr2-SrBr2-H2O at 323 K. Journal of Chemical and Engineering Data, 2019, 64, 3436-3443.

[44] Nie G., Sang S., Cui R., Solid-liquid equilibrium phase diagram and calculation in the quaternary system (KBr-NaBr-MgBr2-H2O) at 298K. Journal of Solution Chemistry, 2019, 48, 862-874.

[45] Liu Z., Zhou Y., Guo M., Lv B., Wu Z., Zhou W., Experimental and theoretical investigations of Cs+ adsorption on crown ethers modified magnetic adsorbent. Journal of Hazardous Materials, 2019, 371, 712-720.

[46] Qian F., Guo M., Qian Z., Li Q., Wu Z., Liu Z., Highly lithium adsorption capacities of H1.6Mn1.6O4 ion-sieve by ordered array structure. ChemistrySelect, 2019, 4, 10157-10163.

[47] Xu N., Li S., Guo M., Qian Z., Li W., Liu Z., Synthesis of H4Mn5O12 nanotubes lithium ion sieve and its adsorption properties for Li+ from aqueous solution. ChemistrySelect, 2019, 4, 9562-9569.

[48] Shi P., Luo S., Voit B., Appelhans D., Zan X., A facile and efficient strategy to encapsulate the model basic protein lysozyme into porous CaCO3. Journal of Materials Chemistry B, 2018, 6, 4205-4215.

[49] Qian Z., Wang S., Ye X., Liu Z., Wu Z., Corrosion resistance and wetting properties of silica-based superhydrophobic coatings on AZ31B Mg alloy surfaces, Applied Surface Science, 2018, 453, 1-10.

[50] Yu X., Zhao C., Zhang T., Liu Z., Molecular and dissociative O2 adsorption on the Cu2O (111) surface. Physical Chemistry Chemical Physics, 2018, 20, 20352-20362.

[51] Fu L., Wang A., Su W., Zheng Y., Liu Z., A rapid electrochemical sensor fabricated using silver ions and graphene oxide. Ionics, 2018, 24, 2821-2827.

[52] Yu X., Zhang X., Meng Y., Zhao Y., Li Y., Xu W., Liu Z., CO adsorption, dissociation and coupling formation mechanisms on Fe2C (001) surface. Applied Surface Science, 2018, 434, 464-472.

[53] Liu Z., Yu R., Dong Y., Li W., Lv B., The adsorption behavior and mechanism of Cr(VI) on 3D hierarchical a-Fe2O3 structures exposed by (001) and non-(001) planes. Chemical Engineering Journal. 2017, 309, 815-823.

[54] Liu Z., Yu R., Dong Y., Li W., Zhou W., Preparation of a-Fe2O3 hollow spheres, nanotubes, nanoplates and nanorings as highly efficient Cr(VI) adsorbents. RSC Advance, 2016, 6, 82854-82861.

[55] Xu N., Liu Z., Dong Y., Hong T., Li D., Li W., Controllable synthesis of mesoporous alumina with large surface area for high and fast fluoride removal, Ceramics International, 2016, 42, 15253-15260.

[56] Xu N., Liu Z., Bian S., Dong Y., Li W., Preparation of MnO2-Al2O3 adsorbent with large specific surface area for fluoride removal. Particuology, 2016, 27, 66-71.

[57] Liu Z., Chiang C., Li W., Zhou W., The role of surface hydrolysis of ferricyanide anions in crystal growth of snowflake-shaped α-Fe2O3. Chemical Communications, 2015, 51, 9350-9353.

[58] Yu F., Liu Z., Zhou W., Facile Synthesis of (110) Plane exposed Au microflowers as high sensitive hydrogen peroxide sensors. European Journal of Inorganic Chemistry, 2015, 15, 2528-2533.

[59] Wang Y., Liu Z., Li D., Liu Z., Dong Y., Li W., Li N., The polymeric nanofilm of triazinedithiolsilane fabricated by self-assembled technique on copper surface. Part 1: Design strategy and corrosion resistance. Corrosion Science. 2015, 98, 382-390.

[60] Liu Z., Lv B., Xu Y., Li W., Hexagonal α-Fe2O3 nanorods bound by high-index facets as high-performance electrochemical sensor. Journal of Materials Chemistry A, 2013, 1, 3040-3046.

[61] Liu Z., Lv B., Xu Y., Wu D., Sun Y., Magnetic and electrochemical behavior of rhombohedral α-Fe2O3 nanostructures with (104) dominant facets. Particuology, 2013, 11, 327-333.

[62] Liu Z., Lv B., Wu D., Zhu Y., Sun Y., Precisely tailoring dendritic α-Fe2O3 structures along [10-10] directions. CrystEngComm, 2012, 14, 4074-4080.

[63] Liu Z., Lv B., Wu D., Sun Y., The preparation and properties of octodecahedral α-Fe2O3 nanoparticles enclosed by {104} and {112} facets. European Journal of Inorganic Chemistry, 2012, 25, 4076-4081.

[64] Liu Z., Lv B., Wu D., Sun Y., Morphology and magnetic properties of α-Fe2O3 particles prepared by octadecylamine-assisted hydrolythermal method. Particuology, 2012, 10, 456-461.

(2) Patents

[1]     Tubular Cobalt Potassium Ferrocyanide Adsorbent, Its Preparation Method, and Application: ZL202311766359.5, April 19, 2024.

[2]     Impurity Removal Method for Crude Salt Lake Products Based on Flow Capacitive Deionization Technology: ZL202310236816.3, July 4, 2023.

[3]     Method for Separation and Extraction of Valuable Resources Lithium, Rubidium, Cesium, Bromine, and Iodine from Salt Lakes: ZL202310236769.2, July 7, 2023.

[4]     Electrochemical Lithium Extraction Electrode and Electrochemical Lithium Extraction Method: ZL202310236709.0, August 8, 2023.

[5]     Lithium Adsorbent, Its Preparation Method, and Lithium Extraction Method: ZL202210838498.3, June 2, 2023.

[6]     Lithium Adsorption Material, Its Preparation Method, and Application: ZL202210825473.X, June 23, 2023.

[7]     Preparation Method for Carbon-Based Lithium Adsorption Electrode for Extracting Lithium from Liquid Resources: ZL202111124050.7, September 22, 2023.

[8]     Carbon-Based Adsorbent Particles for Lithium Extraction from Liquid Resources, Their Preparation Method, and Preparation Device: ZL202111124046.0, September 22, 2023.

[9]     Preparation Method for Aluminum-Based Adsorbent Particles for Lithium Extraction from Liquid Resources: ZL202011340822.6, May 23, 2023.

[10] Preparation Method for Lithium Ion Sieve Adsorbent Particles for Lithium Extraction from Liquid Resources: ZL202011346001.3, June 10, 2022.

[11] Solid-Liquid Reaction Stirrer with Ball-Milling Function and Its Stirring Apparatus: ZL202021933898.5, May 7, 2021.

[12] Preparation Method for Lithium Ion Adsorption Material: ZL202010479045.7, July 28, 2023.

[13] Preparation Method for Lithium Ion Sieve: ZL201911281225.8, February 7, 2023.

[14] Conductive Aluminum-Based Lithium Ion Adsorption Column Material and Its Preparation Method: ZL201910456296.0, February 26, 2021.

[15] Composite Lithium Ion Adsorption Column Material and Its Preparation Method: ZL201910456297.5, November 2, 2021.

[16] Hexagonal Branch-Like Manganese-Based Lithium Ion Sieve Adsorbent and Its Preparation Method: ZL201811494538.7, March 16, 2021.

[17] Porous Manganese-Based Lithium Ion Sieve Adsorbent and Its Preparation Method: ZL201811494510.3, July 16, 2021.

[18] Hexagonal Plate-Like Manganese-Based Lithium Ion Sieve Adsorbent and Its Preparation Method: ZL201811495626.9, April 2, 2021.

[19] Lithium Extraction Method Using Segmented Adsorption Device: ZL201811055794.6, August 24, 2021.

[20] Segmented Adsorption-Desorption Device and Its Application: ZL201811056310.X, April 2, 2021.

[21] Lithium Extraction Method Using Magnetic Microporous Lithium Adsorbent: ZL201811047676.0, June 9, 2020.

[22] Magnetic Microporous Lithium Adsorbent, Its Preparation Method, and Application: ZL201811047604.6, February 23, 2021.

[23] Cesium Ion Adsorbent and Its Preparation Method: ZL201610952849.8, September 10, 2019.

[24] Preparation Method for ZnO: ZL201610886392.5, January 9, 2018.

[25] Cesium Ion Adsorbent and Its Preparation Method: ZL201510880941.3, June 26, 2018.

[26] Cesium Ion Adsorbent and Its Preparation Method: ZL201510880707.0, November 7, 2017.

[27] Cesium Ion Adsorbent and Its Preparation Method: ZL201510880723.X, May 11, 2018.

[28] Magnetic Cesium Ion Adsorbent and Its Preparation Method: ZL201510880748.X, December 15, 2017.

[29] Magnetic Cesium Ion Adsorbent and Its Preparation Method: ZL201510880972.9, January 16, 2018.

[30] Preparation Method for 5Zn(OH)2·2ZnSO4: ZL201510827401.9, March 22, 2017.

[31] Method for Preparing Zinc Borate Crystals from Boric Acid Zinc Whisker Mother Liquor: ZL201410383598.7, May 11, 2016.

[32] Preparation Method for Basic Magnesium Hypochlorite: ZL202310945619.9, November 17, 2023.

[33] Preparation Method for Magnesium-Lithium-Strontium Alloy Based on Molten Salt Co-Deposition: ZL202310413838.2, April 18, 2023.

[34] Preparation Method for Double Electric Layer Composite Nanofiltration Membrane: ZL202010482734.3, July 19, 2022.

[35] Preparation Method for Permanently Hydrophilic Uniform Pore Ultrafiltration Membrane: ZL202110843413.6, June 17, 2022.

7. Awards and Honors

[1]    Qinghai Province Natural Science Excellent Academic Paper Award (2015-2016) - First Prize (First Author).

[2]     Shanxi Provincial Science and Technology Award (2016, Natural Science Category) - First Prize (Second Contributor).

[3]     China Particle Society Natural Science Award (2018) - Second Prize (Second Contributor).

[4]     Youth Scholar for Regional Development, Chinese Academy of Sciences.

[5]     "Kunlun Talent - High-end Innovation and Entrepreneurship Talent" Leading Talent, Qinghai Province.

[6]     Discipline Leader in Natural Science and Engineering, Qinghai Province.

[7]     Youth Innovation Promotion Association of the Chinese Academy of Sciences.

[8]     "Western Light" Youth Scholar A-Class Talent Program.

 

 




Annex: